PVC heat stabilizers environmental protection is imperative

PVC heat stabilizers environmental protection is imperative, zinc-based, non-toxic and organic compounds based heat stabilizer is the main direction of development, but the zinc-based nontoxic heat stabilizers promote the use of a more realistic and market space. Currently, hot zinc-based high-performance, non-toxic heat stabilizer stable performance of foreign brands have approached or reached the level of conventional Chrolinated polyethylene  toxic species, there are many domestic manufacturers are also carried out to promote the development and application of zinc-based nontoxic heat stabilizers, although the overall performance of domestic products to be improved, but there are a lot of products to achieve industrial application, and has appeared in some of the higher levels of high-performance products. But
, The current ratio of domestic consumption of environmentally friendly heat stabilizer is still small, the main reason lies in the use of toxic products, compared with the cost also significantly higher. Seen in this light, the future development of environmentally friendly heat stabilizers, in addition to further improve the performance, you should also focus on improving value for money. To protect the health and survival of our people, the environment and improve the international competitiveness of China's PVC industry and related industries to the EU in urgent need of peer learning, take practical measures and steps to promote the development and Titanium dioxide rutile  application of environmentally friendly process heat stabilizers.
Heat stabilizers are a class of polymers can prevent or reduce the heat in the course of processing and degradation or cross-linking occurs, extending the life of composite additives. Usual stabilizers can be divided into categories according to the main component of salt, fatty acid soaps, organotin compounds, heat stabilizers, and the pure compound classes of organic compounds.
1) Heat stabilizer salt: salt stabilizer is the combination of the "base" of lead salts of inorganic and organic acids, such stabilizer having excellent heat resistance, weather resistance and electrical insulating properties, low cost transparency is poor, there is a certain toxicity, dosage is generally 0.5% to 5.0%. (Source Global polyurethane network)
2) a fatty acid-based heat stabilizer: Such a thermal stabilizer is a compound consisting of a fatty acid with  Metal stearate a metal ion root, also known as hot metal soap stabilizers, its performance and the kind of metal ions and acid radicals, generally in an amount of 0.1% ~ 3.0%.
3) organotin heat stabilizers: class PVC heat stabilizer molecule with chlorine atoms to form unstable ligand and the ligand organotin carboxylate group and a chlorine atom unstable replacement. Features such heat stabilizers are high stability, good transparency, heat resistance, the downside is expensive.
4) composite heat stabilizer: PVC compound stabilizer is a metal salt or soap as a kind of liquid or solid based compound and an organic tin-based compound, wherein the metal salts are calcium - magnesium - zinc, barium - calcium - zinc, barium - zinc and barium - cadmium; common organic acids such as organic acids, naphthenic acid, oleic acid, benzoic acid and salicylic acid. 5) a thermal stabilizer compounds: Except for a few of such primary heat stabilizer stabilizer may be used alone (primarily nitrogen containing organic compound), but also a high boiling point include polyhydric alcohols and phosphites, phosphates and often stabilizer, the metal can improve the weather resistance, transparency of the composite material, to improve the surface color of the article.

The main uses of plastics processing aids and recipes

1 , inorganic non-halogen flame retardants account for an important position among alumina trihydrate and magnesium hydroxide mixed use, you can use a large amount of alumina trihydrate endothermic ( absorbs heat of crystallization water vapor ) , inhibition of the burning surface temperature ; use of magnesium hydroxide to raise the  oxygen index and promote charring effect, because the surface of the polymer film can also play with the charring prevent burning effect. In addition , the development of new varieties of antimony oxide is also a non- halogen flame retardant development in another direction . Plasticizers ; are added to plastics to Flame retardant  increase the system without affecting the plastic nature of the material properties of the polymer . External plasticizer : generally applied to the polymerization system less volatile high-boiling liquid or low melting solids . Plasticizers : the polymer is introduced during the polymerization to reduce the crystallinity of the polymer chain increases the plasticity of the second monomer material plastics. Primary plasticizer ; both molecules inserted in the amorphous region of the polymer plasticizer is inserted while the crystalline regions , which is also called a plasticizer solvent plasticizer . Auxiliary plasticizer ; inserted only partially crystalline molecular plasticizer amorphous regions of the polymer , the plasticizer, the plasticizer is also called non-solvent . Compatibility: the ability to dissolve the plasticizer and resin mixed with each other , and is one of the most basic requirements of plasticizer . Cohesive energy density (CED): energy per unit volume of solvent evaporation . Solubility parameters : the square root organic pigments  of the value of the energy of vaporization per unit volume of solvent. Cloud point (Tc): dilute homogeneous polymer solution and a plasticizer , at a temperature becomes cloudy during cooling . By measuring the cloud point can be estimated plasticizer and resin compatibility. The lower the cloud point , a plasticizer compatible with the polymer , the better. Plasticizing efficiency ; plasticizing efficiency of the resin reaches a certain degree of softness is called the amount of plasticizer plasticizer . Plasticizing efficiency is a relative value , the plasticizer can be used to compare the plasticizing effect . The method used for representing plasticizing efficiency glass transition temperature (Tg) and reduce the decrease in modulus is represented . Oxidation of the polymer is the time increases with the decrease of the performance of the polymer , also known as auto-oxidation . Into the induction period , a strong oxidizing period . Antioxidants ; refers to polymers by oxidation and slow the aging phenomenon can play the role of a class of chemicals. Primary antioxidant ; antioxidant is considered to be the main cleaning agent, a free radical , it is through the coupling reaction ( i.e., the termination reaction) to give a hydrogen atom or to prevent the damaging effects of free radicals in the polymer . Secondary antioxidants ; role of antioxidants is to help decompose the peroxide oxidation of the resulting polymer . Antioxidants including an aid phosphite 2 , 3 thioether antioxidants , metal deactivators metal ion deactivators ; preventing the heavy metal ion induced oxidation of the resulting polymer material , often referred to as metal ions blunt agent or a metal deactivator , a metal chelating agent , also known as copper inhibitors. Stabilizer: to prevent or retard the polymer during processing, storage and use of chemical aging deterioration . Thermal stabilizers ; mainly for PVC and other chlorine-containing polymers , which will not affect the processing and application , but also a certain degree of thermal decomposition of delaying the action of a class of additives. Light stabilizers ; Where can inhibit or slow down the aging of optical oxygen substance called ultraviolet light stabilizer or stabilizers . Radical scavengers : a class of piperidine derivatives light stabilizer with steric effects , referred to as hindered amine light stabilizer (HALS) - aging or photoaging : molecular material long-term or short-term exposure to the sun set under strong fluorescence , due to absorption of UV energy , causing auto-oxidation reaction , leading to degradation of the polymer , making the products discoloration, brittleness , performance degradation , which can not be reused. This process is called oxidative aging or photoaging light flame retardants ; able to increase the flame resistance of the material substance called flame retardants. They are mostly first periodic table V, compound VII and combustion speed of the group III element : refers to the length of the sample per unit time of combustion . Synergistic effect : refers to two or more with the use of additives , the total effect is greater than the sum of the individual effects when used alone . Synergy system : complex flame retardant with the use of the interaction between the flame-retardant to improve performance , the system is called a synergistic effect . Synergistic systems commonly antimony - halogen system , phosphorus halide system, phosphorus - nitrogen system . Burning speed: denotes the length of the sample per unit time of combustion . Burning speed is horizontal and vertical burning combustion method to measure too . Oxygen index: refers to the sample continued to burn like a candle shape , nitrogen - oxygen mixed gas stream must minimum oxygen content. External friction : polymer materials during the molding process , the polymer melt friction between the surface and processing  PVC stabilizer equipment . Friction : polymer material during the molding process , the molten polymer molecules exist between friction. Lubricants ; polymer to reduce friction and external friction , improved melt flow plastics , polymer material during processing to prevent the sticking of the device to ensure the surface smoothness of the added substance called lubricant. Lubricants : prior to processing the plastic ingredients , add a certain compatibility with the polymer lubricant and uniformly dispersed into the material , can reduce the friction between the resin molecules sky lubrication. External lubrication in two ways: one is in the polymer material forming the lubricant coated on the surface processing apparatus , allowed to melt at processing temperatures , and the metal surface of a " thin layer " is formed , the plastic melt and processing equipment to isolate, without adhering to the equipment, or ease of stripping off the roll ; another is compatible with the polymer is very small , it is easy to migrate from inside the polymer during processing on the surface, thereby forming a spacer layer material , before the processing of the ingredients added to the plastic dispersion , and migration to the surface during processing , providing lubrication . Mold release agent: Mold and machining the workpiece remain completely chemically inert substance called a release agent . Blowing agents ; make a class of blowing agents are liquid or plastic state within a certain viscosity range of rubber, plastic material forming the microporous structure. Foaming additives: foaming process , and can be used with the blowing agent and to adjust the rate of decomposition of the blowing agent and decomposition temperature of the substance , or to improve the foaming process , the foam stability of the foam structure and improving the quality of the antistatic substance agent ; added to the resin , attached to the fuel or coated plastics , synthetic polymer material surface to prevent static electricity and liquid fuels hazard a class of chemical additives referred to as antistatic agents topical antistatic agents : the use of a coating , spray , dipping or the like so that it is attached to the plastic surface of the fiber , the durability is poor, it is also called temporary antistatic agent. In the antistatic agent used ( or kneaded antistatic agent ) : in the resin during processing ( or in the monomer during polymerization ) was added to the resin composition of an antistatic agent , because it has good durability , and called permanent antistatic agent. Coupling ; are able to improve between the filler and polymer material properties of a class of substances interface . There are two functional groups in its molecular structure : one can react with the polymer matrix , or at least a good chemical compatibility ; another forming a chemical bond with the inorganic filler . Colorants ; changes in the polymer product was added color additives to improve product appearance coloring power : means affect the ability of the paint colors mixed materials , coloring force, the smaller the amount of toner used , the cost is low . Tinting strength toner with their own characteristics , generally , the toner particle size is reduced , increasing the hiding power of the coloring power : the colorant prevents the penetration of light colored products , in other words , the problem is pointed to the size of the toner transparency , the greater the opacity , transparency worse. Mobility: the colorant to the media to material in contact bleeding or migration phenomenon. In general , inorganic salts of organic acids ( lake pigment ) migration is relatively small ; higher molecular weight were relatively low by migration of small . AR agent ; improve the transparency of the crystalline polymer additive generally used in polypropylene plastic , since the crystallization rate of the PP melt is relatively slow , large spherulites are formed easily , thus affecting its transparency. AR agents can join spherulites become microcrystalline structure , improve its transparency. Fluorescent brightener : plastics can increase the whiteness , brightness, making the colors more vibrant substance called optical brighteners. Can absorb invisible ultraviolet light , blue light into longer wavelength visible light or purple . Fungicides : ( biological inhibitors ) inhibit the growth of mold and mildew killing function . Fungicides suitable plastics mainly phenolic compounds , organometallic compounds , halogen-containing organic compounds, sulfur-containing organic compounds such as anti-fogging agent : also known as flow drops , the transparent material to prevent damage of a fog additives . Aging: In forming polymer materials , storage, structural changes in the use of the process, gradually lose value phenomenon fill in the blank plastic by nature : thermoplastics, thermosetting plastics. By Use : Universal plastics, engineering plastics . The production process of plastic , polymer, additives, processing equipment are the three main material condition. The main factors affecting the plasticizing analysis: polymer molecular force ( dispersion forces , induced forces and orientation force ) , the degree of crystallinity hydrogen plasticizer , PVC polymer resin is mainly used . Plasticizers increase presses reason : lubricating gel , free volume theory . The theory is generally considered : the plasticized polymer materials , is due to inter- molecular chain of the polymer material weaken the role of aggregation caused . Plasticizer molecules inserted between the polymer chains , the polymer chains between gravity weakens , increasing the mobility of the polymer chains , reduces the crystallinity of the polymer chains , thereby increasing the plastic polymer .

PVC external lubricants in providing high-quality PVC products for human

We all know that since industrialization in a long period of time . Most of the use of plastic materials is based on the production of soft PVC products ( such as soft leather, toys, etc. ) based, and the production of soft products rarely require an auxiliary lubricant . Therefore, the titanium dioxide anatase  use of the variety and quantity of lubricant inside and outside are very limited. With the continuous development of industrial technology in a variety of raw materials for PVC hard products ( such as tubes, sheets, plates , profiles , etc. ) have been developed rapidly , and these different hardware products due to different processing equipment and technology needs , whether it is for the PVC lubricant from the variety and quantity requirements are made ​​more so , this demand will continue to promote the development and production of the lubricant products. After you add the right amount of lubricant in PVC , can reduce the friction between macromolecules between PVC and PVC particles melt before the melt ; reduce friction between the melt and PVC plastic mechanical contact between surfaces . PVC amount of lubricant can improve melt flow , increase productivity , and to prevent friction and heat caused by the degradation of PVC , PVC products to improve the appearance quality .
 With the expansion of the application of PVC products , green ideas for everyone continue to enhance the health of plastics additives , transparency , processability and put forward  Zinc stearate strict requirements, which thus contributing to the development and application of the new PVC lubricants . In recent years , PVC lubricants developed rapidly, the proportion of consumption is also on the rise.
PVC external lubricants to provide mankind with high quality PVC products indispensable role . But its product structure adjustment constantly changing , new technology development at a faster rate , an endless stream of new varieties , more sophisticated means of detection , evaluation method is more reasonable. If you do not pay attention  Optical brightener to the production of lubricants to the green direction, then the lubricant ring true when bound to be eliminated. Therefore, the proper use of lubricants is critical to the healthy development of the plastics industry . To accomplish this, the production of lubricants businesses should work hard in the restructuring of production . Promote environmentally friendly non-toxic lubricant inside and outside .

pvc internal and external lubricant selection principles to develop new direction

pvc internal and external lubricant selection principles
(1) pvc external lubricants generally lower than the melting point of the molding processing temperature 50-60 ℃.
( 2 ) to be reasonable taking into account liquidity, the rate of release of plastics and plasticizers . To balance the internal and external lubricants .
Early ( 3 ) to maintain the system, metaphase, anaphase lubrication integrity.
( 4 ) do not adversely affect the secondary processing ( heat sealing , laminating , printing, etc. ) .
( 5 ) the lubricant in the resin PVC stabilizer for fittings  dispersion, the dispersant is added when necessary. ( 6 ) to pay attention to the interaction with other additives ( plasticizers , heat stabilizers , antioxidants , fillers , impact , etc. ) is .
pvc internal and external lubricant previously mainly used for PVC in recent years, the rapid growth in the amount of polyolefins and engineering plastics , the required amount is close to the amount of PVC . Currently , in use , many plastics factory has its own proprietary formula. Recently , the application of polymer blends alloys are widely used, the demand for these products will have great growth. And homopolymer, copolymer compared to the lubricant composition and formulations vary , according to the special requirements of users in research and development , which is a new direction for the development of pvc internal and external lubricant . Production profiles, sheet extrusion , injection molding products , hollow products , blow film are highly transparent products have a high degree of plasticizing , high Aluminum hydroxide  liquidity , and therefore require a higher plasticizing rate, so the pvc to more lubricants ; pipe and for the purpose of producing , in its plasticization is preferably 60% to 70% [ 8 , 9 ] , which requires a low rate of some plasticizer , the lubricant should be relatively little outside ; for calendering process , in order to melt the PVC calender rolls easily peeled , external lubricant should be a little more ; while the injection molding process will have as little as possible with external lubricant for external lubrication to minimize the impact of falling weld line strength .
PVC external lubrication balanced Titanium dioxide rutile  diversity in fact different types of processing equipment, such as extrusion ( divided into single and twin screw ) , injection molding, calendaring , require different lubrication balance. Strictly speaking, the same equipment , products of different manufacturers , and even the same device with the new balance of old have different lubrication requirements . Different types of products , such as pipes, films, sheets and profiles , and have different lubrication balance.

Calcium stearate uniform fine white powder

Calcium stearate uniform fine white powder. Melting point 145 ℃. Dissolved in toluene, ethanol, benzene and other organic solvents, insoluble in water. When heated to 400 ℃ slowly decomposed, flammable, met decomposition of stearic acid and corresponding calcium salt. There are absorbent, non-toxic.
Edit this paragraph purposes: heat stabilizers for PVC and other plastic processing lubricants, mold release agents and the like. In rigid products, and the base of lead salts, lead soap can increase the rate of gelation. Also used in food packaging, medical equipment and  Chrolinated polyethylene other requirements of non-toxic soft film and equipment. Can be made of polyethylene, polypropylene, halogen absorbers to eliminate the adverse effects of residual catalyst on the color and stability. As plasticizers in rubber processing, enabling natural rubber and synthetic rubber to soften the whole, and almost no effect on curing. Also used as polyolefin fibers and molded plastic lubricants, grease thickening agent, textile  aluminium stearate waterproofing agent, paint flatting agent, plasticizer manufacturing plastic labels and so on. Also used in pencil manufacturing and medicine, perfume industry. Calcium Stearate Formula: (C17H35COO) 2Ca Molecular Weight: 606 CAS NO.1592-23-0 gravity: 1.08 Technical Specifications: Index name Premium grade First grade Second grade calcium content% 6.5 ± 0.5 6.5 ± 0.6 6.5 ± 0.7 free acid (stearic acid)% ≤ 0.5 0.5 0.5 Heating loss% ≤ 2.0 3.0 3.0 Melting point ℃ 149-155 ≥ 140 ≥ 125 fineness (0.075mm sieve)% ≥ 99.5 99.0 99.0 impurities (grain) ≤ 6 12 - Micro residue (0.063mm sieve remaining)% ≤ 1.0 1.0 1.0 Whiteness% ≥ 95 90 -
Polyolefins, polyolefin acid neutralizer color stability and corrosion with direct contribution; lubricating / processing aluminium stearate  aids improve the polyolefins, polyamides, styrene-based rubber, and extrusion molding (film, fibers, copying, etc.), and press molding workability. For release of thermoplastics, thermoset rubber, and articles, such as polyurethane foam and an unsaturated polyester.

types of composite stabilizer

 Are generally pale yellow to yellow-brown oily liquid, specific gravity of 1.0-1.1 at room temperature, good heat resistance, pollution from sulfur, epoxy plasticizers and stabilizing effect can be improved by, blowing it with the activated species with . 2 liquid calcium zinc complexes
Because of the different components, varied in nature, usually pale yellow to yellow clear oily liquid at room  plastic flame retardant temperature gravity of 1.0-1.05. It is non-toxic PVC stabilizer, mainly for food packaging films, containers leather foam stabilizers. 3 basic components include: (1) a barium salt - can be alkylphenols Ba 2 - ethylhexanoate and barium laurate (composite powder used), benzoic acid and substituted benzoic acid barium neodecanate barium. Accounting for 6-7% of the barium salt of the compound, i.e., the proportion of cadmium is approximately 2:1-32 (metal note, the percentage by weight, hereinafter the same).
(2) cadmium salt - may be 2 - ethylhexanoate, cadmium laurate, cadmium, cadmium oleate, phenyl, and substituted benzoic acid, cadmium naphthenate, cadmium, cadmium neodecanoate. Approximately 3-4% of the cadmium complexes. (3) zinc salt - may be 2 - ethylhexanoate, zinc laurate (composite powder used), zinc naphthenate, zinc neodecanoate, and substituted benzoic acid such as zinc. 0.5-1% zinc in the composite.
4) aliphatic phosphite - may be triphenyl phosphite, diphenyl phosphite, an octyl diphenyl phosphite, a decyl phosphite, tris (nonylphenyl) and the like. Phosphite approximately 15-20% (by weight) in the composite, as chelating agents.
(5) Other - includes a small amount organic pigments  of 2,6 - tert-butyl-p-cresol, bisphenol A, nonyl phenol antioxidant and an ultraviolet absorber, and the liquid paraffin, white oil, diesel oil, spindle oil mineral oil solvent, and the need small amount of antifoaming agent such as a higher alcohol.
Liquid barium cadmium zinc composite stabilizer due to the composition of different nature are different. But is typically a pale yellow to yellow clear liquid, specific gravity 0.95 to 1.02 at room temperature, a viscosity less than 100 centipoise at about freezing point -15 ℃. Liquid barium cadmium zinc cadmium and barium liquid similar to have excellent thermal, light stability, initial color small, good transparency and color stability. Stabilizing effect than their solid soaps strong composite, the dosage can be reduced, usually 2-3 parts, dust poisoning does not occur, and completely dissolved in the plasticizer in general, good dispersibility, little tendency to precipitate. Wherein the liquid barium cadmium zinc early color liquid barium cadmium smaller than some.
4 low lead salt stabilizer price, good thermal stability, has been widely used, but small lead salt powder, and mixing the ingredients, the dust is inhaled it can cause lead poisoning, for which they developed a scientific and technical personnel new types of composite lead salt heat stabilizer. This symbiotic compound additive reaction techniques using three salts, metal salts and soaps in the reaction system to the nascent lubricants and various grain sizes are mixed in order to ensure sufficient heat dispersion stabilizer in the PVC system , and because of the melting of the lubricant particles, but also to avoid the poisoning caused by lead dust. Inclusive of the lead salt stabilizer compound required for processing heat stabilizer component and a lubricant component, the whole package is referred to as a heat stabilizer. It has the following advantages:
(A) the various components of the composite Flame retardant  heat stabilizer may be fully mixed in the production process, the resin is mixed with a significant improvement in the uniformity of the dispersion.
(2) mixing the formulation and simplify the measurement of frequency, to reduce the probability of loss and the resulting measurement error is brought about.
(3) simplicity of the materials supply and reserve conducive to production and quality management. (4) provide the possibility of clean production of products, improve production conditions.
In short, the composite heat stabilizer scale production conducive to the development of lead salt heat stabilizer provides a new direction. An important indicator of lead salt composite stabilizer is the content of lead, lead salt composite stabilizer lead content of current production is generally 20% -60%; usage in the production of PVC plastic window profiles for 3.5-6 parts

environmentally friendly non-toxic polymer composite lubrication P-80B significant performance

Efficient and environmentally friendly non-toxic polymer composite lubrication P-80A is a nontoxic compound efficient lubrication products. Efficient and environmentally friendly non-toxic Glycerol monostearate  polymer composite lubrication is Jianhong lubricant formulations plant the introduction of international advanced technology and processes, using imported raw materials and foreign PVC plastic manufacturing process and material properties, polymer developed excellent internal and external lubricant. Overcome the lack of trouble and slip agents processing performance on the traditional monomer. Add this product safe to use, easy to mix, more stable performance, reasonable adjustment formula in the case, has the following  Diethylene glycol dibenzoate remarkable properties:
1, reducing the coefficient of friction between molecules and promote plasticizing, stable and appropriate to reduce the amount of system products; has a good stripping effect, enhancing the surface finish and scratch resistance;
2, the melting point of the product is a wide range of PVC materials significantly enhance the free flow of processing and non-sticky, and thus increase productivity, reduce equipment wear and energy consumption, reduce product defect rate;
3, significant improvement fillers, pigments and other additives in the PVC dispersion resin, may be a corresponding increase in the amount of filler, and to products, color stability, increase the gloss;
4, the product both inside and outside  tio2 anatase of the late lubrication before PVC processing, within the recommended dosage is not blooming, no precipitation, with good stability.
Efficient and environmentally friendly non-toxic polymer composite lubrication P-80A Scope:
Efficient and environmentally friendly non-toxic polymer composite lubrication P-80A is widely used in non-transparent sheet